Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst. Kinetic, isotopic, and infrared studies on well-defined dispersed Pt clusters are combined here with first-principle theoretical methods on model cluster surfaces to probe the mechanism and structural requirements for CO oxidation catalysis at conditions typical of its industrial practice. Pt and Co3O4 supported on ceria and zirconia for the catalytic reduction of N2O in the presence of CO. Yanan Wang, Sihang Liu, Chunlei Pei, Qiang Fu, Zhi-Jian Zhao, Rentao Mu, Jinlong Gong. clusters: amorphization and role of the support material in a highly active CO oxidation catalyst. Selective catalytic reduction of NO structure relaxation by force fitting. Shushuang Li, Fuzerong Wang, Yongmei Liu, Yong Cao. Industrial & Engineering Chemistry Research. management contact at your company. Measured rate parameters for CO oxidation were independent of Pt cluster size; these parameters depend on the ratio of rate constants for O2 reactions with CO* and CO adsorption equilibrium constants, which reflect the respective activation barriers and reaction enthalpies for these two steps. Mónica García-Diéguez, David D. Hibbitts. Leo DeRita, Joaquin Resasco, Sheng Dai, Alexey Boubnov, Ho Viet Thang, Adam S. Hoffman, Insoo Ro, George W. Graham, Simon R. Bare, Gianfranco Pacchioni, Xiaoqing Pan, Phillip Christopher. Thomas Klint Hansen, Martin Høj, Brian Brun Hansen, Ton V. W. Janssens, Anker Degn Jensen. Satoshi Tsukuda, Akira Idesaki, Masaki Sugimoto, Shu Seki, Takahisa Omata. A systematic investigation of the geometries, electronic and magnetic properties of Al Yanhong Zhang, Xuefei Weng, Huan Li, Haobo Li, Mingming Wei, Jianping Xiao, Zhi Liu, Mingshu Chen, Qiang Fu, and Xinhe Bao . Precise Control of Pt Particle Size for Surface Structure–Reaction Activity Relationship. Behzad Tangeysh, Clarke Palmer, Horia Metiu, Michael J. Gordon, Eric W. McFarland. Influence of Adsorbates on the Electronic Structure, Bond Strain, and Thermal Properties of an Alumina-Supported Pt Catalyst. Reem Al-Shareef, Moussab Harb, Youssef Saih, Samy Ould-Chikh, Dalaver H. Anjum, Jean-Pierre Candy. Gold octamers (Au 8) bound to oxygen-vacancy F-center defects on Mg (001) are the smallest clusters to catalyze the low-temperature oxidation of CO to … Moskaleva, M. Bäumer, K.M. Environmental Materials beyond and below the Nanoscale: Single-Atom Catalysts. Golubina, T.N. Anlong Kuang, Miao Mo, Minquan Kuang, Biao Wang, Chunling Tian, Hongkuan Yuan, Guangzhao Wang, Hong Chen. Hydrogen spillover in the Fischer–Tropsch synthesis: An analysis of platinum as a promoter for cobalt–alumina catalysts. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Utilizing Quantitative in Situ FTIR Spectroscopy To Identify Well-Coordinated Pt Atoms as the Active Site for CO Oxidation on Al2O3-Supported Pt Catalysts. Spectroscopy Identification of the Bimetallic Surface of Metal–Organic Framework-Confined Pt–Sn Nanoclusters with Enhanced Chemoselectivity in Furfural Hydrogenation. Wei-Zhen Li, Lei Nie, Yingwen Cheng, Libor Kovarik, Jun Liu, Yong Wang. I think that your value for the heat of combustion of CO is incorrect. The Role of Reducible Oxide–Metal Cluster Charge Transfer in Catalytic Processes: New Insights on the Catalytic Mechanism of CO Oxidation on Au/TiO2 from ab Initio Molecular Dynamics. Xingbang Hu, Youting Wu, Zhibing Zhang. Colloidal nanoparticle size control: experimental and kinetic modeling investigation of the ligand–metal binding role in controlling the nucleation and growth kinetics. Chunrong Yin, Fabio R. Negreiros, Giovanni Barcaro, Atsushi Beniya, Luca Sementa, Eric C. Tyo, Stephan Bartling, Karl-Heinz Meiwes-Broer, Sönke Seifert, Hirohito Hirata, Noritake Isomura, Sandeep Nigam, Chiranjib Majumder, Yoshihide Watanabe, Alessandro Fortunelli, Stefan Vajda. In Situ Oxidation Study of Pt Nanoparticles on MgO(001). Structure sensitivity via decoration of low-coordination exposed metal atoms: CO oxidation catalysis on Pt clusters. Density Functional Theory Study of the Water Dissociation on Platinum Surfaces: General Trends. Catalytically active PdRu and CuRu bimetallic nanoparticle formation in the mesoporous SiO2 by supercritical CO2-assisted immobilization. CO oxidation over Pt/Cr1.3Fe0.7O3 catalysts: Enhanced activity on single Pt atom by H2O promotion. O Ex-situ up-conversion of biomass pyrolysis bio-oil vapors using Pt/Al2O3 nanostructured catalyst synergistically heated with steel balls via induction. 3 Mesoporous Co–Fe–O nanocatalysts: Preparation, characterization and catalytic carbon monoxide oxidation. Anatoly I. Frenkel, Michael W. Cason, Annika Elsen, Ulrich Jung, Matthew W. Small, Ralph G. Nuzzo, Fernando D. Vila, John J. Rehr, Eric A. Stach, Judith C. Yang. Mikhail Mamatkulov and Jean-Sébastien Filhol . Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles. E.V. He Wang, Tonghao Shen, Sai Duan, Zheng Chen. Xian-Yan Xu, Jing Li, Huiying Xu, Xianfang Xu, Cunyuan Zhao. Ranganathan Krishnan, Wan-Sheng Su, Hsin-Tsung Chen. for low-temperature CO oxidation: study of the CO–O CO oxidation on Pt nanoclusters, size and coverage effects: a density functional theory study. Theoretical estimates of rate and equilibrium constants for surface reactions and CO adsorption show that both parameters increase as the coordination of exposed Pt atoms decreases in Pt201 cluster surfaces; such compensation dampens but does not eliminate coordination and cluster size effects on measured rate constants. Journal of Molecular Catalysis A: Chemical. The most likely place you will come across them is in organic chemistry. CO adsorption on a Pt(111) surface partially covered with FeO x nanostructures. Ted Krapkat, 42 years experience as an industrial chemist in cement & aluminium industries. Sodium is a reducing agent while oxygen is an oxidising agent. This material is available free of charge via the Internet at http://pubs.acs.org. Yun Liu, Fan Yang, Yanxiao Ning, Qingfei Liu, Yi Zhang, Hao Chen, Xinhe Bao. Bingping Liu, Jin Yong Lee, Shihai Yan. Carbon monoxide oxidation activities over Cu, Cu 2 O, and CuO were studied to seek insight into the role of the copper species in the oxidation reaction. Find more information about Crossref citation counts. Critical review: Effects of complex interactions on structure and dynamics of supported metal catalysts. by CO over LaMnO3 nano perovskites prepared by microwave and ultrasound assisted sol–gel method. Sompoch Jongsomjit, Paweena Prapainainar, Korakot Sombatmankhong. (OH) Recent Advances of Ceria‐Based Materials in the Oxidation of Carbon Monoxide. Effect of phase interaction on catalytic CO oxidation over the SnO2/Al2O3 model catalyst. A DFT Study of the CO Oxidation Mechanism on AlnAu (n = 1–12) Clusters. Single-Atom Catalysis of O Yu Wang, Huan-Huan Liu, Shu-Yuan Wang, Meng-Fei Luo, Ji-Qing Lu. Jian-Liang Cao, Gao-Jie Li, Yan Wang, Guang Sun, Xiao-Dong Wang, Bala Hari, Zhan-Ying Zhang. Ting Wang, Jin-Yuan Xing, Ai-Ping Jia, Cen Tang, Yue-Juan Wang, Meng-Fei Luo, Ji-Qing Lu. Denise Chan, Steffen Tischer, Jasmin Heck, Claudia Diehm, Olaf Deutschmann. Information about how to use the RightsLink permission system can be found at redistribute this material, requesters must process their own requests via the RightsLink permission Structure–activity relationships of Pt/Al2O3 catalysts for CO and NO oxidation at diesel exhaust conditions. V. Petkov, L. Yang, J. Yin, R. Loukrakpam, S. Shan, B. Wanjala, J. Luo, K. W. Chapman, C. J. Zhong. Nitrogen-doped penta-graphene as a superior catalytic activity for CO oxidation. Lais R. Borges, Alejandro Lopez‐Castillo, Debora M. Meira, Jean Marcel R. Gallo, Daniela Zanchet, José Maria C. Bueno. When the material was exposed to the environment that contains oxygen at elevated temperature, cemented carbide occurred the following oxidation: (4) WC (s) + 5/2O 2 (g) = WO 3 (s) + CO 2 (g) (5) Co (s) + 2/3O 2 (g) = 1/3Co 3 O 4 (s) (6) Co (s) + WC (s) +3O 2 (g) = CoWO … Institutional subscribers have access to the current volume, plus a Highly active subnano Rh/Fe(OH) catalyst for preferential oxidation of CO in H2-rich stream. 2 Metal oxidation takes place when an ionic chemical reaction occurs on a metal's surface while oxygen is present. Yes, Cheng Cheng et al 2019 J. The overall preferential CO oxidation (PROX) reaction can be depicted as: CO + H 2 + 1/2 O 2 → CO 2 + H 2. 2 A combined in-situ XAS–DRIFTS study unraveling adsorbate induced changes on the Pt nanoparticle structure. R. Wróbel, S. łagonda, U. Narkiewicz, R. Pełech, S. Becker, L. Szymaszkiewicz. First-Principles Investigations of Single Metal Atoms (Sc, Ti, V, Cr, Mn, and Ni) Embedded in Hexagonal Boron Nitride Nanosheets for the Catalysis of CO Oxidation. Synthesis and characterization of Pt/CeOx systems for catalytic CO oxidation reaction. A versatile approach for quantification of surface site fractions using reaction kinetics: The case of CO oxidation on supported Ir single atoms and nanoparticles. –hGO) – a first-principles calculation. Matthew J. Kale and Phillip Christopher . This article has been corrected. Adsorption and sensing behaviors of SF6 decomposed species on Ni-doped C3N monolayer: A first-principles study. Porous Organic Polymer-Templated Porous Copper-Ceria with Highly Dispersed Copper Oxide and Excellent Activity for CO Oxidation. Sunyoung Oh, Hyunwoo Ha, Hanseul Choi, Changbum Jo, Jangkeun Cho, Hyuk Choi, Ryong Ryoo, Hyun You Kim, Jeong Young Park. Yang-Gang Wang, Yeohoon Yoon, Vassiliki-Alexandra Glezakou, Jun Li, and Roger Rousseau . Electrons move from the metal to the oxygen molecules during this process. Non-noble, efficient catalyst of unsupported α-Cr2O3 nanoparticles for low temperature CO Oxidation. 2 Infrared measurements of the stretch vibration of CO … Joaquin Resasco, Sheng Dai, George Graham, Xiaoqing Pan. Catalytic Consequences of Chemisorbed Oxygen during Methanol Oxidative Dehydrogenation on Pd Clusters. $\ce{Co}$ is known to have two possible oxidation numbers in solution : +II and +III. Activating low-temperature diesel oxidation by single-atom Pt on TiO2 nanowire array. Wanlin Fu, Yunqian Dai, Jerry Pui Ho Li, Zebang Liu, Yong Yang, Yibai Sun, Yiyang Huang, Rongwei Ma, Lan Zhang, and Yueming Sun . Ab Initio Density Functional Calculations and Infra-Red Study of CO Interaction with Pd Atoms on θ-Al2O3 (010) Surface. Sippakorn Wannakao, Nongnuch Artrith, Jumras Limtrakul, Alexie M. Kolpak. Defective Nb2O5-supported Pt catalysts for CO oxidation: Promoting catalytic activity via oxygen vacancy engineering. 2 Guangran Xu, Jiayin Liu, Baocang Liu, Jun Zhang. Superior Catalytic Performance of Atomically Dispersed Palladium on Graphene in CO Oxidation. Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts. Meanwhile, the high selectivity is achieved because H2 hardly takes part in the reaction, and the good activity is obtained since the CO with moderate binding strength could be smoothly removed at various CO concentration. Find out more. Roles of niobium in the dehydrogenation of propane to propylene over a Pt/Nb-modified Al Screened for originality? O is in the second column to the left of the noble gases so it has a -2 charge. Effect of Pd/Pt ratio on the reactivity of methane catalytic combustion in bimetallic Pd-Pt catalyst. David D. Hibbitts, Romel Jiménez, Masayuki Yoshimura, Brian Weiss, Enrique Iglesia. Y.P. q Hyung Jun Kim, Myeong Gon Jang, Dongjae Shin, Jeong Woo Han. Ultrafine Pt nanoparticles supported on a dendrimer containing thiol groups: an efficient catalyst for the synthesis of benzimidazoles and benzothiazoles from benzyl alcohol derivatives in water. the Mott–Schottky effect. http://pubs.acs.org/page/copyright/permissions.html. If you have a user account, you will need to reset your password the next time you login. Catalytic CO oxidation of palladium nanoparticles formed by one-step synthesis on polycarbosilane nanowires. catalyst by hydrogen treatment for low-temperature CO oxidation. Enhancing Au/TiO2 Catalyst Thermostability and Coking Resistance with Alkyl Phosphonic-Acid Self-Assembled Monolayers. Adsorption of SO2 and NO2 molecule on intrinsic and Pd-doped HfSe2 monolayer: A first-principles study. 3 Approximate Hessian for accelerating Effects of Catalyst Model and High Adsorbate Coverages in ab Initio Studies of Alkane Hydrogenolysis. 3 The difficulty is to obtain highly selective oxidation of CO while leaving H 2 unreacted. Na Li, Qiu-Yan Chen, Liang-Feng Luo, Wei-Xin Huang, Meng-Fei Luo, Geng-Shen Hu, Ji-Qing Lu. Please choose one of the options below. Oxygen vacancy promoted CO oxidation over Pt/CeO 2 catalysts: A reaction at Pt–CeO 2 interface. Getting Insights into the Temperature-Specific Active Sites on Platinum Nanoparticles for CO Oxidation: A Combined in Situ Spectroscopic and ab Initio Density Functional Theory Study. Seyed Ali Hosseini, Behrouz Mehri, Aligholi Niaei, Behrang Izadkhah, Consuelo Alvarez-Galvan, Jose G. Luis Fierro. These conclusions are consistent with the lack of isotopic scrambling in C16O−18O2−16O2 reactions, and with infrared bands for chemisorbed CO that did not change within a CO pressure range that strongly influenced CO oxidation turnover rates. Jinshuo Zou, Zhichun Si, Yidan Cao, Rui Ran, Xiaodong Wu, and Duan Weng . Chemisorption of CO and Mechanism of CO Oxidation on Supported Platinum Nanoclusters, Department of Chemical Engineering, University of California, Berkeley, California 94720, United States, Nanostellar, Inc., 3696 Haven Avenue, Redwood City, California 94063, United States, Departments of Chemical Engineering and Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States, Division of Chemical Sciences, E. O. Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States. Andreas M. Gänzler, Maria Casapu, Alexey Boubnov, Oliver Müller, Sabrina Conrad, Henning Lichtenberg, Ronald Frahm, Jan-Dierk Grunwaldt. Elena M. Slavinskaya, Lidiya S. Kibis, Olga A. Stonkus, Dmitry A. Svintsitskiy, Andrei I. Stadnichenko, Elizaveta A. Fedorova, Anatolii V. Romanenko, Vasyl Marchuk, Dmitry E. Doronkin, Andrei I. Boronin. Charging of the supported clusters plays a key role in promoting their chemical activity. Pt nanoparticles supported on SBA-15: Synthesis, characterization and applications in heterogeneous catalysis. phase oxidation of ethylbenzene with molecular oxygen to acetophenone with Co/Mn/Br (MC-type) catalyst system could be demonstrated by the enhancement of the catalytic activity and thus selectivity towards acetophenone 16 and suppression of side reactions. We also studied the particle size dependence of the CO oxidation ability of the Rh nanoparticles, because Rh is known to be an excellent catalyst for the oxidation of CO in car exhaust gas. Development of highly active and selective PROX catalysts is highly desirable but proved to be extremely challenging. Highly Catalytic Electrochemical Oxidation of Carbon Monoxide on Iridium Nanotubes: Amperometric Sensing of Carbon Monoxide. Ningqiang Zhang, Lingcong Li, Rui Wu, Liyun Song, Lirong Zheng, Guizhen Zhang, Hong He. Acidic effect of porous alumina as supports for Pt nanoparticle catalysts in Combining In-Situ Transmission Electron Microscopy and Infrared Spectroscopy for Understanding Dynamic and Atomic-Scale Features of Supported Metal Catalysts. Oxidation of surface-bound Mn2+ and the theorized Mn(III)-oxide was slow relative to Co(II)EDTA2− oxidation, and a reversible loss in the oxidative ability of … competitive adsorption and active oxygen species. Isolated Platinum Atoms Stabilized by Amorphous Tungstenic Acid: Metal-Support Interaction for Synergistic Oxygen Activation. Composites for CO Oxidation Based on Thermal Treatment. This would give the correct value of -110 kJ for the heat of formation of CO. in NH Nanocatalysis II: In Situ Surface Probes of Nano-Catalysts and Correlative Structure–Reactivity Studies. Anna V. Perdikaki, Anastasios I. Labropoulos, Eirini Siranidi, Ioannis Karatasios, Nikos Kanellopoulos, Nikos Boukos, Polycarpos Falaras, Georgios N. Karanikolos, Georgios E. Romanos. Shanrong Zou, Hirotaka Yokoyama, Yasuhiro Sugawara. Chaitanya K. Narula, Lawrence F. Allard, Zili Wu. Chenxi Dong, Xupeng Zong, Wenshuai Jiang, Lijuan Niu, Ziwen Liu, Dan Qu, Xiayan Wang, Zaicheng Sun. Peixin Li, Runduo Zhang, Xiaodong Wang, Shanshan Liu, Ning Liu, Biaohua Chen. Jiaming Cai, Jie Zhang, Kun Cao, Miao Gong, Yun Lang, Xiao Liu, Shengqi Chu, Bin Shan, and Rong Chen . Mohammad Abu-Laban, Pranjali D. Muley, Daniel J. Hayes, Dorin Boldor. Chan Ho Jung, Jaecheol Yun, Kamran Qadir, Dahee Park, Jung Yeul Yun, Jeong Young Park. As CO is a possible by-product in VOC oxidation (as not always complete oxidation of the pollutant to CO 2 takes place), the study of CO oxidation is also important in this context. Saeed Mozaffari, Wenhui Li, Mudit Dixit, Soenke Seifert, Byeongdu Lee, Libor Kovarik, Giannis Mpourmpakis, Ayman M. Karim. Catalytic consequences of the identity and coverages of reactive intermediates during methanol partial oxidation on Pt clusters. Xiao Liu, Yuanting Tang, Meiqing Shen, Wei Li, Shengqi Chu, Bin Shan, Rong Chen. CO-Induced Scavenging of Supported Pt Nanoclusters: A GISAXS Study. Lu Li, Yan-Zhou Wang, Xiao-Xu Wang, Ke-Ke Song, Xiao-Dong Jian, Ping Qian, Yang Bai. Form and we will follow up with your librarian or Institution on your behalf. 2 Baolin Liu, Yizhao Li, Yali Cao, Lei Wang, Shaojun Qing, Kun Wang, Dianzeng Jia. Qian Zhang, Xi-Xi Qin, Fan-Peng Duan-Mu, Hui-Ming Ji, Zhu-Rui Shen, Xiao-Peng Han, Wen-Bin Hu. © 2019 IOP Publishing Ltd For permission to reproduce, republish and Promoting Pt catalysis for CO oxidation 4 Stakheev, Dmitry A. Bokarev, Igor P. Prosvirin, Valerii I. Bukhtiyarov. for CO Oxidation at Cryogenic Temperatures. 3 Size Dependence of Charge State of Pd Nanoparticles on the Al2O3/NiAl(110) Surface by Kelvin Probe Force Microscopy. Unraveling the Role of Metal–Support Interactions in Heterogeneous Catalysis: Oxygenate Selectivity in Fischer–Tropsch Synthesis. You will only need to do this once. CO Catalytic Oxidation of Pt-Loaded Perovskite BaTiO3 Near Ferroelectric-Phase Transition Temperature. n Acta Metallurgica Sinica (English Letters). Brett T. Loveless, Corneliu Buda, Matthew Neurock, and Enrique Iglesia . Promotion of Pt/CeO S. M. Yin, J. J. Duanmu, Y. H. Zhu, Y. F. Yuan, S. Y. Guo, J. L. Yang, Z. H. Ren, G. R. Han. Interfacial parameters of Pt/γ-Al2O3: A first-principle and MD simulation study. Si-Min Yin, Jia-Jie Duanmu, Yong-Feng Yuan, Shao-Yi Guo, Zhi-Chao Zhu, Zhao-Hui Ren, Gao-Rong Han. Nihong An, Ping Wu, Suying Li, Mingjun Jia, Wenxiang Zhang. In-situ ATR-IR study of surface reaction during aqueous phase reforming of glycerol, sorbitol and glucose over Pt/γ-Al2O3. Hongling Guan, Jian Lin, Botao Qiao, Xiaofeng Yang, Lin Li, Shu Miao, Jingyue Liu, Aiqin Wang, Xiaodong Wang, Tao Zhang. Synergistic Pt-WO3 Dual Active Sites to Boost Hydrogen Production from Ammonia Borane. Oxidation states refer to atoms or ions, not compounds. catalyst. Hui Wang, Jinshi Dong, Lawrence F. Allard, Sungsik Lee, Se Oh, Jun Wang, Wei Li, Meiqing Shen, Ming Yang. On the other hand, only CO2 and H2O were produced by the complete oxidation of CH4 over Fe and Co catalysts. Kozhevin, D.A. We already found that PtCu IMC supported on silica gel was more active than Pt/SiO2for the preferential oxidation (PROX) of CO in excess hydrogen. Mixed Electron–Proton Conductors Enable Spatial Separation of Bond Activation and Charge Transfer in Electrocatalysis. Bifunctional CO oxidation over Mn-mullite anchored Pt sub-nanoclusters Shyam Kattel, Binhang Yan, Jingguang G. Chen, Ping Liu. Hongye Cheng, Ingvar Kvande, Yi-An Zhu, Nina Hammer, Magnus Rønning, John C. Walmsley, Ping Li, Zhiwen Qi, Xing-Gui Zhou. The role of nanoparticle size and ligand coverage in size focusing of colloidal metal nanoparticles. DME, propane and CO: The oxidation, steam reforming and WGS over Pt/Al2O3. Pt/oxide nanocatalysts synthesized via the ultrasonic spray pyrolysis process: engineering metal–oxide interfaces for enhanced catalytic activity. (Hans) Niemantsverdriet, Michael Claeys, Eric van Steen. Ya-Huei(Cathy) Chin, Corneliu Buda, Matthew Neurock, and Enrique Iglesia . Design of Ceria Catalysts for Low‐Temperature CO Oxidation. Soeren Porsgaard, Luis K. Ono, Helene Zeuthen, Jan Knudsen, Joachim Schnadt, Lindsay R. Merte, Jacques Chevallier, Stig Helveg, Miquel Salmeron, Stefan Wendt, Flemming Besenbacher. Therefore, the oxidation state of oxygen was found to be -2 and the oxidation number of carbon is +4 in a carbon dioxide molecule.
2020 oxidation of co